Alright, if a strict RAW says no, should a character that multiclasses into wizard and takes Acolyte or Adept Power gain that ability? Preparing spells, after all, is a defining feature of a wizard and it would be kind of strange for a character who is multi-ing as a wizard to not prepare spells.
Also, I’ll point out that a character who takes Arcane Initiate and has Wis 13 (or higher) already qualifies for Expanded Spellbook. However, since only wizards prepare spells, it’s of dubious value since it will run into the same issue that sparked my original question.